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( h) 0 ) ' R - " L - ( - ( # ( ( # ) - j h : Alkenlar olinish usullari
Alkanlarni degidridlash va krekinglash ushbu usul sanoat usuli bolib, alkenlar alkanlar molekulasidan ikki atam H ajratib olish orqali olinadi.bunday reaksiyalar yuqori haroratda va xar xil metallarning oksidlari katolizatorligida amalga oshadi
CH3CH2 CH2 CH2 CH3 QUOTE CH3CH= CH CH2 CH3 + H2
Galagenalkanlardan galagen vodorod yoki galagen ajratib chiqarish
RCH2CH2Br + NaOH ! [ R C H 2 C H 2 O H ] R C H = C H 2 + N a B r + H 2 O
R C H 2 C H 2 C l Q U O T E R C H = C H 2 + H C l
R C H ( B r ) - C H ( B r ) - R + Z n ! R C H = C H R + Z n B r 2
S p i r t l a r n i d e g i s r a t l a s h . 2 x i l y o l b i l a n a m a l g a o s h i r i l a d i 1 - u s u l H 2 S O 4 b i l a n q i z d i r i l a d i b u a s o s a n l a b o r a t o r i y a u s u l i x i s o b l a n a d i .
C H 3 C H 2 O H QUOTE CH2=CH2 + H2O
2-usulda spirtlar qattiq katalizatorlar, odatda Al2O3 ishtirokida qizdiriladi.
CH3CH2OH QUOTE CH2=CH2 + H2O bu metod sanoatda ham qolaniladi.
Diyenlar va alkinlarni gidridlash Ni katolizator ishtirokida
CH2=CH-CH=CH2 + H2 QUOTE CH3-CH=CH-CH3
R C a"C R + H 2 Q U O T E R C = C R
A l k e n l a r o l i n i s h u s u l l a r i
A l k a n l a r n i d e g i d r i d l a s h v a k r e k i n g l a s h u s h b u u s u l s a n o a t u s u l i b o l i b , a l k e n l a r a l k a n l a r m o l e k u l a s i d a n i k k i a t a m H a j r a t i b o l i s h o r q a l i o l i n a d i . b u n d a y r e a k s i y a l a r y u q o r i h a r o r a t d a v a x a r x i l m e t a l l a r n i n g o k s i d l a r i k a t o l i z a t o r l i g i d a a m a l g a o s h a d i
C H 3 C H 2 C H 2 C H 2 C H 3 Q U O T E C H 3 C H = C H C H 2 C H 3 + H 2
G a l a g e n a l k a n l a r d a n g a l a g e n v o d o r o d y o k i g a l a g e n a j r a t i b c h i q a r i s h
R C H 2 C H 2 B r + N a O H ! [ R C H 2 C H 2 O H ] R C H = C H 2 + N a B r + H 2 O
R C H 2 C H 2 C l Q U O T E R C H = C H 2 + H C l
R C H ( B r ) - C H ( B r ) - R + Z n ! R C H = C H R + Z n B r 2
S p i r t l a r n i d e g i s r a t l a s h . 2 x i l y o l b i l a n a m a l g a o s h i r i l a d i 1 - u s u l H 2 S O 4 b i l a n q i z d i r i l a d i b u a s o s a n l a b o r a t o r i y a u s u l i x i s o b l a n a d i .
C H 3 C H 2 O H Q U O T E C H 2 = C H 2 + H 2 O
2 - u s u l d a s 1 Y r t ! " # % & ͿyyjyjYyjYyjYyj h h CJ OJ QJ mH sH h CJ H*OJ QJ mH sH h CJ OJ QJ mH sH h CJ OJ QJ mH sH hb6 CJ OJ QJ mH sH hf CJ OJ QJ mH sH h,1 CJ OJ QJ mH sH h2 CJ OJ QJ mH sH h ` CJ OJ QJ mH sH #he/ hWb 5CJ OJ QJ mH sH #he/ h ` 5CJ OJ QJ mH sH K H
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ŸŤyk]L]=. hGy CJ H*OJ QJ mH sH h$ CJ H*OJ QJ mH sH h$ h$ CJ OJ QJ mH sH h$ CJ OJ QJ mH sH hGy CJ OJ QJ mH sH h6 CJ OJ QJ mH sH he# CJ H*OJ QJ mH sH he# CJ OJ QJ mH sH 'h,% he# CJ H*OJ PJ QJ mH sH j 8 h,% h,% EHU0j h1 R h,% CJ H*OJ PJ QJ UmH sH 'h1 R h,% CJ H*OJ PJ QJ mH sH jR& h,% h,% EHU
, ` l p r v x
䧙||cOBOc jI h,% h,% EHU'h1 R h,% CJ H*OJ PJ QJ mH sH 0j h1 R h,% CJ H*OJ PJ QJ UmH sH hE CJ OJ QJ mH sH h:6 CJ H*OJ QJ mH sH h$ CJ OJ QJ mH sH h:6 CJ OJ QJ mH sH hX}O CJ H*OJ QJ mH sH #he/ ha+ 5CJ OJ QJ mH sH ha+ CJ OJ QJ mH sH hX}O CJ OJ QJ mH sH h_ CJ OJ QJ mH sH
' Q R S U n p ŲŲŞxfXIXIX; h - CJ OJ QJ mH sH ha+ CJ H*OJ QJ mH sH ha+ CJ OJ QJ mH sH #he/ ha+ 5CJ OJ QJ mH sH $h,% h:6 CJ OJ PJ QJ mH sH $h,% h - CJ OJ PJ QJ mH sH 'h,% h - CJ H*OJ PJ QJ mH sH $h,% hE CJ OJ PJ QJ mH sH 'h,% hE CJ H*OJ PJ QJ mH sH 0j h1 R h,% CJ H*OJ PJ QJ UmH sH jI\ h,% h,% EHU p q s t w x ɵɛɇttttatS@ $h,% h\ CJ OJ PJ QJ mH sH h{ CJ OJ QJ mH sH $h,% h~ CJ OJ PJ QJ mH sH $h,% h - CJ OJ PJ QJ mH sH 'h,% h - CJ H*OJ PJ QJ mH sH j h,% h,% EHUjn h,% h,% EHU'h1 R h,% CJ H*OJ PJ QJ mH sH 0j h1 R h,% CJ H*OJ PJ QJ UmH sH h - CJ OJ QJ mH sH h - CJ H*OJ QJ mH sH
&
Ǯl[I[ #h+ h+ CJ H*OJ QJ mH sH h+ h+ CJ OJ QJ mH sH 'h,% h+ CJ H*OJ PJ QJ mH sH jV h,% h,% EHUj^ h,% h,% EHU'h1 R h,% CJ H*OJ PJ QJ mH sH 0j h1 R h,% CJ H*OJ PJ QJ UmH sH h+ CJ OJ QJ mH sH h{ CJ OJ QJ mH sH h\ CJ H*OJ QJ mH sH h\ CJ OJ QJ mH sH &
'
( * , . 0 2 6 8 B D ӫ}iUG9 h+ CJ OJ QJ mH sH hk CJ OJ QJ mH sH 'h,% hk CJ H*OJ PJ QJ mH sH 'h,% h7 CJ H*OJ PJ QJ mH sH jS h,% h,% EHUjN h,% h,% EHU'h1 R h,% CJ H*OJ PJ QJ mH sH 0j h1 R h,% CJ H*OJ PJ QJ UmH sH h7 CJ H*OJ QJ mH sH h7 CJ OJ QJ mH sH h~ CJ H*OJ QJ mH sH h+ CJ H*OJ QJ mH sH D F H j ѿѰѰѰѰѰrerXD 'h,% he/ CJ H*OJ PJ QJ mH sH j h,% he/ EHUjX h,% he/ EHU'he/ he/ CJ H*OJ PJ QJ mH sH 0j he/ he/ CJ H*OJ PJ QJ UmH sH h he/ CJ OJ QJ mH sH he/ CJ H*OJ QJ mH sH #he/ he/ 5CJ OJ QJ mH sH he/ CJ OJ QJ mH sH h - CJ OJ QJ mH sH $h,% h CJ OJ PJ QJ mH sH P R T V X Z \ ^ ` b d f h j B 2 3 3 $a$gde/ gde/
& F gde/ $a$gde/ gd:6
" $ & ⦒xd 'h,% he/ CJ H*OJ PJ QJ mH sH ju h,% he/ EHUj h,% he/ EHU'he/ he/ CJ H*OJ PJ QJ mH sH 0j he/ he/ CJ H*OJ PJ QJ UmH sH #h!T he/ CJ H*OJ QJ mH sH h he/ CJ OJ QJ mH sH he/ CJ OJ QJ mH sH he/ CJ H*OJ QJ mH sH '& 2 4 p r $ & yeReReReR$h,% he/ CJ OJ PJ QJ mH sH 'h,% he/ CJ H*OJ PJ QJ mH sH j= h,% he/ EHUj@+ h,% he/ EHU'he/ he/ CJ H*OJ PJ QJ mH sH 0j he/ he/ CJ H*OJ PJ QJ UmH sH #he/ he/ 5CJ OJ QJ mH sH h$ he/ CJ OJ QJ mH sH he/ CJ H*OJ QJ mH sH he/ CJ OJ QJ mH sH 2 P2 R2 T2 X2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 ߵs`s`s`s``ߵ $h,% he/ CJ OJ PJ QJ mH sH 'h,% he/ CJ H*OJ PJ QJ mH sH j\d h,% he/ EHUjP h,% he/ EHU'he/ he/ CJ H*OJ PJ QJ mH sH 0j he/ he/ CJ H*OJ PJ QJ UmH sH he/ CJ H*OJ QJ mH sH Uhe/ CJ OJ QJ mH sH #he/ he/ 5CJ OJ QJ mH sH %p i r t l a r q a t t i q k a t a l i z a t o r l a r , o d a t d a A l 2 O 3 i s h t i r o k i d a q i z d i r i l a d i .
C H 3 C H 2 O H Q U O T E C H 2 = C H 2 + H 2 O b u m e t o d s a n o a t d a h a m q o l a n i l a d i .
D i y e n l a r v a a l k i n l a r n i g i d r i d l a s h N i k a t o l i z a t o r i s h t i r o k i d a
C H 2 = C H - C H = C H 2 + H 2 Q U O T E C H 3 - C H = C H - C H 3
R C a"C R + H 2 Q U O T E R C = C R
T a r q a t m a m a t e r i a l
E t i l e n n i n g o l i n i s h i
T o z a p r o b i r k a g a o l d i n d a n t a y y o r l a b q o y i l g a n e t i l s p i r t i b i l a n k o n s e n t r l a n g a n s u l f a t k i s l o t a a r a l a s h m a s i d a n 1 , 5 2 m l s o l i b , p r o b i r k a n i g a z o t k a z u v c h i n a y l i t r u b k a b i l a n t u t a s h t i r i n g . S p i r t a l a n g a s i d a q i z d i r i n g . A r a l a s h m a b i r m e y o r d a q a y n a s h i u c h u n k i c h k i n a b o l a k g o v a k m a t e r i a l ( p e m z a ) t a s h l a n g . P r o b i r k a d a g i a r a l a s h m a q a y n a y b o s h l a g a n d a , g a z o t k a z u v c h i t r u b k a n i n g i k k i n c h i u c h i n i b o s h q a p r o b i r k a d a g i b r o m s u v i g a b o t i r i n g . B u n d a b r o m s u v i n i n g r a n g i a s t a - s e k i n y o q o l a d i ( 6 - r a s m ) .
3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4 4 &4 (4 *4 ,4 .4 04 64 B4 ŸŤssdsdsWJŤs j h,% he/ EHUj h,% he/ EHU he/ CJ H*OJ QJ mH sH he/ CJ OJ QJ mH sH #h+ he/ CJ H*OJ QJ mH sH h+ he/ CJ OJ QJ mH sH 'h,% he/ CJ H*OJ PJ QJ mH sH j h,% he/ EHU0j he/ he/ CJ H*OJ PJ QJ UmH sH jx h,% he/ EHU'he/ he/ CJ H*OJ PJ QJ mH sH 3 3 B4 D4 F4 H4 J4 L4 N4 P4 R4 T4 V4 X4 Z4 \4 ^4 `4 b4 d4 f4 h4 j4 4 4 4 $d 7$ 8$ H$ a$gd'$ gd:6 gde/ $a$gde/ B4 D4 F4 H4 j4 4 4 X5 Z5 5 5 V6 X6 6 6 L7 N7 7 7 7 7 7 8 @8 B8 8 8 8 xbxbxbxbxbxbxbxbxbxbK -j he h'$ CJ OJ QJ UaJ mH sH +h'$ B*CJ OJ QJ mH nHph# sH tH1h$ h'$ B*CJ OJ QJ mH nHph# sH tH7h$ h'$ 5B*CJ OJ QJ \mH nHph# sH tH$h'$ 5CJ( OJ QJ \aJ mH sH h'$ CJ OJ QJ mH sH he/ CJ OJ QJ mH sH ha+ he/ CJ OJ QJ mH sH $h,% he/ CJ OJ PJ QJ mH sH 4 8 8 8 8 8 8 8 gd:6 $d 7$ 8$ H$ a$gd'$ d 7$ 8$ H$ gd'$ 8 8 8 ha+ h'$ CJ OJ QJ mH sH h'$ CJ OJ QJ aJ mH sH , 1h . A!"R#n$n% ) D d
&
3 A " Þ
15 Cr2O3 450 ̊C b {6f)7 *y7! D 6 n {6f)7 *y7!PNG
IHDR z ! r( sRGB pHYs + [IDAThC?v0 Ɲ NP&ґ vc)t*%ǖ vxOHBQ#\Bwsz/4_-zf e(4q0dt9pf{SP &)^1gHeѭ!E`.Ef9isu@s4"9 ڼ'4NcaA"
b4pu]yVUcN JB@4&$a apsm om
[b:;K S4ji&i/]=1r ŸM22{ 6nfV
y]ݍ͏}]}0pM 2[4=6Q!Г vဓБ<供M3z1ŷ6 pʏVy7Wpg [pg%UL-H)v=ׇ+RwĽ _N[\=,_HԴt!oɝ n;R2L /ZCܝ7~SnыewVY݂;+bn@VUnL7 IENDB`) D d
&
3 A " Þ
15 Cr2O3 450 ̊C b {6f)7 *y7! m 6 n {6f)7 *y7!PNG
IHDR z ! r( sRGB pHYs + [IDAThC?v0 Ɲ NP&ґ vc)t*%ǖ vxOHBQ#\Bwsz/4_-zf e(4q0dt9pf{SP &)^1gHeѭ!E`.Ef9isu@s4"9 ڼ'4NcaA"
b4pu]yVUcN JB@4&$a apsm om
[b:;K S4ji&i/]=1r ŸM22{ 6nfV
y]ݍ͏}]}0pM 2[4=6Q!Г vဓБ<供M3z1ŷ6 pʏVy7Wpg [pg%UL-H)v=ׇ+RwĽ _N[\=,_HԴt!oɝ n;R2L /ZCܝ7~SnыewVY݂;+bn@VUnL7 IENDB` D d
3 A " Õ
15 t ̊ b `g? z & 6 n r `g?PNG
IHDR 5 ! t sRGB pHYs + IDATXGM tu`)*7E]*mRhÔ_ae}ߣcg&(Ƙ
b*+>R^>AUTʄ:j<:(-ԺoiPB-n(twr:t\O7ri
OЂK]o45H_" !쟩mķtV jz{ϗoM4< \O&< ^~?nUm^j ZZ IENDB` D d
3 A " Õ
15 t ̊ b `g? z a8 6 n r `g?PNG
IHDR 5 ! t sRGB pHYs + IDATXGM tu`)*7E]*mRhÔ_ae}ߣcg&(Ƙ
b*+>R^>AUTʄ:j<:(-ԺoiPB-n(twr:t\O7ri
OЂK]o45H_" !쟩mķtV jz{ϗoM4< \O&< ^~?nUm^j ZZ IENDB`a D d
3 A " Ô
15 H2SO4 b 5 |I=)
,J 6 n |I=)
PNG
IHDR P
Qh; sRGB pHYs + IDATXGW 4WUs?L+N ׄSApz d@"Ll3
2Fw`5sW%|;+;7cga
|%q6k )u>x~^ w0-Ft6j h6VzDx^`e\[.HhY f"*&bO#SF,a*KT1VLT 94"I" X
vk O Q|9Q|?Ǽ}P_oXj;j|$_t[WvDŽB E
@k%] B6EQ Lu
4rS IENDB`a D d
3 A " Ô
15 H2SO4 b 5 |I=)
\ 6 n |I=)
PNG
IHDR P
Qh; sRGB pHYs + IDATXGW 4WUs?L+N ׄSApz d@"Ll3
2Fw`5sW%|;+;7cga
|%q6k )u>x~^ w0-Ft6j h6VzDx^`e\[.HhY f"*&bO#SF,a*KT1VLT 94"I" X
vk O Q|9Q|?Ǽ}P_oXj;j|$_t[WvDŽB E
@k%] B6EQ Lu
4rS IENDB`Z D d
o
3 A " á
15 Al2O3 (300-350 C) b ! 2fs{ " n 6 n 2fs{ "PNG
IHDR ! >\9 sRGB pHYs + IDAThCY?v0 7= @&ndz.06+K x Iq?佪G$YJUơ8?G^σ?JB=y
1S\sO2ɀ@2+ ru8cu3ob|siKݧP]" EњJ4 `DYĚ)M6e#UY,mcZf}8UGY!3@Rk ђƩ"Š2{mR2ҶtXtO
+L:I,slv&JҰi}|Y.Go!t9S`]YϭXm$5,x:㪛MXlR
@}z#pOJ;{}[
15 Al2O3 (300-350 C) b ! 2fs{ " H 6 n 2fs{ "PNG
IHDR ! >\9 sRGB pHYs + IDAThCY?v0 7= @&ndz.06+K x Iq?佪G$YJUơ8?G^σ?JB=y
1S\sO2ɀ@2+ ru8cu3ob|siKݧP]" EњJ4 `DYĚ)M6e#UY,mcZf}8UGY!3@Rk ђƩ"Š2{mR2ҶtXtO
+L:I,slv&JҰi}|Y.Go!t9S`]YϭXm$5,x:㪛MXlR
@}z#pOJ;{}[
15 Ni b ;J !|^ 6 n ;J !|^PNG
IHDR 5 = sRGB pHYs + 7IDATXGV0Xp TE iJˏЁ0>^ⅈ d3ߑ\˅)`±06
mʔHKC &X5T@G-9pY} Q~ַArL5,5J/ ˞Jv\rجIrخpkDYx |Zg>d鬃BaBZ?`ZK_@otn5\ t<8Q?ǥE<Ӿg]o0mG{Ou~.g߷xzo&>
#GcV G س IENDB` D d
3 A " Ñ
15 Ni b ;J !|^ 6 n ;J !|^PNG
IHDR 5 = sRGB pHYs + 7IDATXGV0Xp TE iJˏЁ0>^ⅈ d3ߑ\˅)`±06
mʔHKC &X5T@G-9pY} Q~ַArL5,5J/ ˞Jv\rجIrخpkDYx |Zg>d鬃BaBZ?`ZK_@otn5\ t<8Q?ǥE<Ӿg]o0mG{Ou~.g߷xzo&>
#GcV G س IENDB` D d
3 A " Õ
15 Pd/PbCO3
b }YrpFMLk 6 n }YrpFMLkPNG
IHDR b ! sRGB pHYs + @IDAThC1v0 @Cϒ2qp҅z0rrn.l#9VpJ2dY$[f4M"OA||[D!Z (&k% Ȋe|ߧbeΠox❩U{u@ZF 64v1P\4 CHE #c&p~cĭ-cFpĖc&N7 ##"iKE!̇ 6= D_⊣v;&۞-J&'/br篽9ܔ\Dž!Utd_lt0+8;QOV|QfNgpj; J{@zonށx@J?
L C*
a9--<kI
lv:-FEXbMp`|$M24 0t'ыnSP\ $Lf:v k.(G zE ]U<{;OBi&9zwI67 zO#NN0RlLA$S %&D H,݃l* IENDB` D d
3 A " Õ
15 Pd/PbCO3 b }YrpFMLk 6 n }YrpFMLkPNG
IHDR b ! sRGB pHYs + @IDAThC1v0 @Cϒ2qp҅z0rrn.l#9VpJ2dY$[f4M"OA||[D!Z (&k% Ȋe|ߧbeΠox❩U{u@ZF 64v1P\4 CHE #c&p~cĭ-cFpĖc&N7 ##"iKE!̇ 6= D_⊣v;&۞-J&'/br篽9ܔ\Dž!Utd_lt0+8;QOV|QfNgpj; J{@zonށx@J?
L C*
a9--<kI
lv:-FEXbMp`|$M24 0t'ыnSP\ $Lf:v k.(G zE ]U<{;OBi&9zwI67 zO#NN0RlLA$S %&D H,݃l* IENDB`) D d
&
3 A " Þ
15 Cr2O3 450 ̊C b {6f)7 *y7! 6 n {6f)7 *y7!PNG
IHDR z ! r( sRGB pHYs + [IDAThC?v0 Ɲ NP&ґ vc)t*%ǖ vxOHBQ#\Bwsz/4_-zf e(4q0dt9pf{SP &)^1gHeѭ!E`.Ef9isu@s4"9 ڼ'4NcaA"
b4pu]yVUcN JB@4&$a apsm om
[b:;K S4ji&i/]=1r ŸM22{ 6nfV
y]ݍ͏}]}0pM 2[4=6Q!Г vဓБ<供M3z1ŷ6 pʏVy7Wpg [pg%UL-H)v=ׇ+RwĽ _N[\=,_HԴt!oɝ n;R2L /ZCܝ7~SnыewVY݂;+bn@VUnL7 IENDB`) D d
&
3 A " Þ
15 Cr2O3 450 ̊C
b {6f)7 *y7! 6 n {6f)7 *y7!PNG
IHDR z ! r( sRGB pHYs + [IDAThC?v0 Ɲ NP&ґ vc)t*%ǖ vxOHBQ#\Bwsz/4_-zf e(4q0dt9pf{SP &)^1gHeѭ!E`.Ef9isu@s4"9 ڼ'4NcaA"
b4pu]yVUcN JB@4&$a apsm om
[b:;K S4ji&i/]=1r ŸM22{ 6nfV
y]ݍ͏}]}0pM 2[4=6Q!Г vဓБ<供M3z1ŷ6 pʏVy7Wpg [pg%UL-H)v=ׇ+RwĽ _N[\=,_HԴt!oɝ n;R2L /ZCܝ7~SnыewVY݂;+bn@VUnL7 IENDB` D d
3 A " Õ
15 t ̊ b `g? z 6 n r `g?PNG
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